Self-organized platinum nanoparticles on freestanding graphene.

نویسندگان

  • Peng Xu
  • Lifeng Dong
  • Mehdi Neek-Amal
  • Matthew L Ackerman
  • Jianhua Yu
  • Steven D Barber
  • James Kevin Schoelz
  • Dejun Qi
  • Fangfang Xu
  • Paul M Thibado
  • Francois M Peeters
چکیده

Freestanding graphene membranes were successfully functionalized with platinum nanoparticles (Pt NPs). High-resolution transmission electron microscopy revealed a homogeneous distribution of single-crystal Pt NPs that tend to exhibit a preferred orientation. Unexpectedly, the NPs were also found to be partially exposed to the vacuum with the top Pt surface raised above the graphene substrate, as deduced from atomic-scale scanning tunneling microscopy images and detailed molecular dynamics simulations. Local strain accumulation during the growth process is thought to be the origin of the NP self-organization. These findings are expected to shape future approaches in developing Pt NP catalysts for fuel cells as well as NP-functionalized graphene-based high-performance electronics.

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عنوان ژورنال:
  • ACS nano

دوره 8 3  شماره 

صفحات  -

تاریخ انتشار 2014